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            "itemType": "journalArticle",
            "title": "Re‐analysis of extensional flow data of polymer melts",
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                    "creatorType": "author",
                    "firstName": "A. V.",
                    "lastName": "Shenoy"
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            "abstractNote": "Extensional flow behaviour is very important in polymer processing operations such as fiber spinning and film blowing but there is scanty experimental data in the literature due to inherent difficulties in measurement of the relevant flow parameters. In the present paper, an attempt has been made to correlate the existing available data on the extensional flow of three generic types of polymer melts through a logarithmic plot of modified extensional viscosity function, ηE · MFI, and a modified extension rate, (ε/MFI)2. The method may be extended to other polymeric systems.\n\nDas Dehnfließverhalten ist sehr wichtig bei polymeren Herstellungsprozessen wie Faserspinnen und Filmblasen, doch es gibt nur spärliche experimentelle Daten in der Literatur wegen der inhärenten Schwierigkeiten bei der Messung der entsprechenden Fließparameter. In dieser Arbeit ist der Versuch gemacht worden, die vorhandenen zugänglichen Daten des Dehnfließens von drei verwandten Typen von Polymerschmelzen durch eine logarithmische Auftragung der modifizierten Dehnviskositätsfunktion ηE · MFI und einer modifizierten Dehngeschwindigkeit (ε/MFI)2, zu korrelieren. Diese Methode kann auf andere Polymersysteme übertragen werden.",
            "publicationTitle": "Angewandte Makromolekulare Chemie",
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            "date": "1985",
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            "pages": "77-84",
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            "DOI": "10.1002/apmc.1985.051350107",
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            "tags": [
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                    "tag": "film blowing"
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                {
                    "tag": "polymer melts"
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            "abstractNote": "The unified viscosity function curves proposed earlier by the authors have an inherent limitation in the low shear rate region. This limitation is the effect of using the melt flow index as a normalizing factor to obtain the coalesced curves, which itself is insensitive to molecular parameters such as molecular weight distribution. A single integral constitutive equation of the BKZ type is used to derive the viscosity function which would be useful in generating unified curves based on the melt flow index but devoid of the limitation of molecular weight distribution effects in the low shear rate region.",
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            "itemType": "book",
            "title": "THERMOPLASTIC MELT RHEOLOGY AND PROCESSING",
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                    "firstName": "A. V.",
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            "abstractNote": "Presents rheological data on a number of polymers, making use of the master curve approach to determine unified curves for each generic type of polymer. The text offers a step-by-step procedure for developing a speadsheet computer program to obtain accurate thermoplastic rheograms at any tempertature without using sophisticated rheometres. It includes possible correlations of melt flow index with various parameters involved in polymer manufacture, product fabrication and property evaluation. Review This book offers an interesting, practical approach to the rheology and processing parameters of thermoplastic materials. . . This book is recommended for engineers and processors who may benefit from the use of the spreadsheet program to predict the behavior of thermoplastic materials as a function of processing parameters. ---Polymer News",
            "series": "",
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            "tags": [
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                    "tag": "melt rheology"
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                    "tag": "plastics engineering"
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                    "tag": "polymer manufacture"
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                    "tag": "polymer processing"
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                    "tag": "polymer rheology"
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                    "tag": "product fabrication"
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            "title": "Simplified calculations for mold-filling during non-isothermal flow of polymer melts",
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                    "firstName": "D. R.",
                    "lastName": "Saini"
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            "abstractNote": "The injection moulder and the mould designer know the importance of operating under minimum pressure drop conditions during cavity filling in a processing operation in order to minimize frozen-in stresses and the clamping forces preventing mould opening. A detailed theoretical calculation of the pressure drop versus flow rate curve as would be obtained by a rheologist for even the simplest geometry would require high technical sophistication and expensive computational and experimental facilities which are beyond the means of the processor. Most often the practical processor takes recourse to simple rules of the thumb based on experience to find solutions to processing problems. Ideally, the theoretical rheologist and the practical processor should work together for mutual benefit. This is possible if simplistic approaches based on sound scientific principles are provided by rheologists to practical processors for finding quick answers to processing problems not through art but through science. In the present paper, such a simplistic approach is suggested for estimating the minimum pressure drop during mould cavity filling based on an order of magnitude approximation technique. The results of the present work derived through an understanding of polymer melt rheology should be useful to the injection moulder when making process changes due to grade variations in the polymer being processed, and also to the mould designer in order to obtain quick estimates of design parameters.",
            "publicationTitle": "Plastic Rubber Processing Applications",
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                    "lastName": "MacDermott"
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            "abstractNote": "The difficult problem of selecting the best thermoplastic resin is made easier by the guidelines presented in this book. Included are methods of ranking the thermoplastics by their properties, price, and processability, along with quick-reference tables of rankings. Example programs for computerized ranking are also included. The problems of matching part design and molding conditions are also addressed. Contents include: (1) the selection process; (2) physical properties; (3) rheological properties; (4) injection molding; (5) prototype parts; (6) estimating part costs; (7) ranking of resins; (8) computerized approach to selection; (9) expert system SELECTHER; (10) resin suppliers; and (11) nomenclature and glossary. Review This is a useful book and will supplement the designer's knowledge and skills when trying to define the most suitable thermoplastics for a specific application. ---Materials & Manufacture",
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            "title": "Rheology of poly(vinyl chloride) formulations from melt flow index measurements",
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            "abstractNote": "A knowledge of the complete flow curve, or rheogram, of a PVC formulation depicting the variation of the melt viscosity over industrially relevant ranges of shear rate and temperature is essential in the design of polymer-processing equipment, process optimization, and troubleshooting. These data are generated on sophisticated rheometers that are beyond the financial and technical means of most PVC processors. The only flow parameter that can be readily measured on an inexpensive apparatus is the melt flow index of the resin-mix. In the present work, a method has been proposed to estimate the rheograms of a PVC formulation at temperatures relevant to its processing conditions with the use of a master curve, knowing the melt flow index and glass-transition temperature of the formulation. A master curve that coalesces rheograms of different PVC formulations at various temperatures has been generated and proposed as a tool for estimating the flow curve.",
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            "pages": "192-197",
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            "DOI": "10.1002/vnl.730050409",
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            "title": "Rheology of nylon 6 containing metal halides",
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                    "firstName": "A. V.",
                    "lastName": "Shenoy"
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            "abstractNote": "Addition of metal halides to nylons has been shown to be advantageous in a number of ways. The decrease in melting temperature, increase in glass transition temperature and melt viscosity by such additions have allowed more convenient processing of low molecular weight polymers and thermally unstable polymers. Rheological data depicting the variation of melt viscosity with shear rate at temperatures relevant to processing are necessary in optimizing and trouble-shooting plastics processing operations. In the present paper, a method has been proposed to estimate, complete flow curves or rheograms of nylon—metal halide systems with the use of a master curve knowing the melt flow index and glass transition temperature of the system. The validity of the approach has been verified for the nylon 6—lithium chloride system and shown to hold good for any nylon—metal halide combination.",
            "publicationTitle": "Journal of Materials Science",
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            "date": "7/1983",
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                    "firstName": "A. V.",
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            "abstractNote": "A method has been proposed earlier by Shenoy et al. to estimate complete flow curves depicting the variation of melt viscosity over industrially relevant range of shear rate and temperature through the use of unified curves characteristic of each generic type of polymer. In the present paper, the unified curves have been fitted through modified forms of already known generalized Newtonian models. The advantage of fitting such rheological models to unified curves lies in the fact that calculations involving entrance length estimates, heat transfer, die design, mold design, etc. are greatly simplified. Knowing the model parameters, one needs to know only the melt flow index, which is a relatively easy parameter to obtain, to make any engineering design calculations. The modified generalized Newtonian models have been fitted to a number of polymers covering one or more from each group of olefinics, styrenics, cellulosics, vinyls and engineering thermoplastics.",
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                    "tag": "entrance lengths"
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                    "tag": "styrenics"
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                    "tag": "unified curves"
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                {
                    "tag": "vinyls"
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            "title": "Rheograms of filled polymer melts from melt-flow index",
            "creators": [
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                    "creatorType": "author",
                    "firstName": "A. V.",
                    "lastName": "Shenoy"
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            "abstractNote": "Polymers filled with extending fillers, such as calcium carbonate or talc, or with reinforcing fillers, such as glass fibers or mica, are increasingly being used in a number of applications. The addition of fillers to a polymer changes the melt rheological behavior of the polymer. A knowledge of the viscosity vs. shear-rate flow curves of the filled system at various temperatures and as a function of filler parameters (such as filler type, shape, and amount) is necessary for process design, optimization, and trouble shooting. The generation of such rheological data is ezpensive and cumbersome in view of the broad range of fillers and the large numbers of filler parameters. In the present article, a unifying approach is proposed that coalesces the flow curves of filled systems of a polymer at various temperatures into a master curve that is independent of the filler parameters. An effective methods is presented to estimate the rheograms of filled systems with the use of a master curve, characteristic of a genetic resin type, knowing the melt-flow index and glass-transition temperature of the system. Master curves have been reported for filled system of low-density polyethylene, high-density polyethylene, poly-propylene polystyrene, nylons, poly(ethylene terephthalate), and polycarbonate.",
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            "pages": "53-63",
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            "title": "Rheograms of cellulosic polymers from the melt flow index",
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                    "lastName": "Shenoy"
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            "abstractNote": "Data on the variation of melt viscosity over a wide range of shear rates and temperatures are necessary in the processing of cellulosic polymers. An effective method has been proposed to estimate the viscosity vs. shear rate flow curves of a cellulosic resin at temperatures relevant to the processing conditions, from its melt flow index and glass transition temperature. The method involves the use of a master curve obtained by coalescing the rheograms of various grades in terms of a modified viscosity, η˙MFI, and a modified shear rate, ˙g/MFI. Master curves have been reported for cellulose esters and ethers.",
            "publicationTitle": "Journal of Applied Polymer Science",
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            "abstractNote": "A method proposed earlier has been extended to estimate complete flow curves or rheograms of engineering plastics. Master curves that are independent of the grade and temperature have been generated and presented for acrylics, polyacetal, nylons, polyethylene terephthalate, polycarbonate and polysulfone. The influence of the various molecular parameters on the viscosity behaviour of polymer melts have been explained rationally. More specifically, the effects of chain branching and of chain rigidity on the master curve of a resin type have been elucidated with reference to polyacetal and polysulfone, respectively. The method presented here can be used effectively by processors of engineering plastics.",
            "publicationTitle": "Rheologica Acta",
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            "date": "3/1983",
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