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            "title": "Kinetic study of rare earth elements extraction from decrepitated magnet powder using liquid magnesium",
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                    "firstName": "Nicolas",
                    "lastName": "Stankovic"
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            "abstractNote": "Extraction of rare earth elements from spent NdFeB magnets with liquid magnesium was investigated using a laboratory scale perfect stirred reactor. Data were processed to model Nd extraction performances for treating decrepitated magnet powder.\n          , \n            This study presents a comprehensive investigation of neodymium extraction from decrepitated magnet powder using liquid magnesium. Neodymium extraction from the decrepitated magnet into the liquid magnesium was assessed between 700 and 900 °C by measuring the average length of the diffusion zone in sintered samples of 3 mm-thickness. Experiments were conducted in a reactor which a design allows a homogeneous distribution of magnesium with efficient agitation. An empirical model was used to model the growth kinetics of the diffusion zone by using the Rosin–Rammler equation and estimate particle size distribution. The results were extrapolated to decrepitated magnet powder particles to simulate the neodymium extraction performances. Remarkably, the treatment time required was relatively short, not exceeding 22 minutes, and varied depending on the extraction target and temperature. Both temperature and the setpoint for the volume rate to be treated emerged as critical factors. Their impact on the process was thoroughly examined and discussed. These findings offer promising insights into the industrial feasibility of the use of liquid magnesium for rare-earth extraction from spent permanent magnet.",
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            "abstractNote": "Abstract\n            Carbonatites, carbon-rich magmatic rocks, are thought to form by low-degree partial melting of a relatively carbon-poor mantle followed by protracted differentiation and immiscibility. However, the nature of parental magmas and the characteristics of the early stages of differentiation that shape the subsequent crystal and liquid lines of descent remain poorly constrained. To provide new constraints, deep crustal cumulative xenoliths from Oldoinyo Lengai (East African Rift), the only active volcano erupting carbonatite magmas, were studied. We use major and volatile elements in primitive olivine-hosted melt inclusions, as well as major and trace elements in crystals, to reconstruct the conditions of formation and evolution of cumulates (pressure, temperature, composition). Xenoliths are composed of olivine, diopside, phlogopite, amphibole and accessory minerals. One remarkable feature is the presence of diopside and phlogopite oikocrysts enclosing roundish olivine chadacrysts. Melt inclusions do not have vapor bubble and have major element compositions resembling olivine nephelinite (7–10 wt % MgO after corrections for post-entrapment crystallization). The absence of vapor bubbles implies that the concentrations of volatile components (i.e. CO2, H2O, S) were not compromised by well-known post-entrapment volatile loss into the vapor bubble. Based on the melt inclusion study by SIMS, the volatile concentrations in olivine nephelinite magmas (early stage of differentiation) at Oldoinyo Lengai were 20–130 ppm S, 390–4500 ppm F, 50–540 ppm Cl, up to 6074 ppm CO2 and up to 1.5 wt % H2O. According to the calculated CO2-H2O saturation pressures and geophysical data, xenoliths from Embalulu Oltatwa document a mushy reservoir in the lower crust. Primitive olivine nephelinite melt inclusions have higher H2O contents than olivine nephelinite lavas from other further South volcanoes from the North Tanzanian Divergence (0.2–0.5 wt % H2O), suggesting that the lithospheric mantle source beneath the Oldoinyo Lengai is more hydrated than the mantle beneath the rest of North Tanzanian Divergence. We present a model in which resorption features observed in olivine chadacrysts, together with the LREE enrichments in olivine grains, are the consequences of reactive porous flows in a deep crustal mushy reservoir. We provide constraints on the major, trace and volatile element composition of the parental magmas of carbonatite series and demonstrate with Rhyolite-MELTS models that phonolites and related natrocarbonatites from Oldoinyo Lengai can be produced by protracted differentiation of olivine nephelinite melts.",
            "publicationTitle": "Journal of Petrology",
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            "pages": "egad084",
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                    "firstName": "Sophie",
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            "abstractNote": "ABSTRACT\n            \n              In phosphorites, the content and distribution of rare earth elements are linked to the environment of phosphogenesis. This paper focuses on the question of sources and processes controlling the rare earth element content of apatite from Belgian phosphorites formed during three major phosphogenic events in the Lower Palaeozoic, Late Cretaceous and Cenozoic. To constrain sources and processes, new data include petrological, mineralogical (including cathodoluminescence and Raman spectroscopy) and\n              in situ\n              trace element and Sr and O isotope analyses of apatite. Fluorapatite from Lower Palaeozoic P‐rich conglomerates has the greatest rare earth element enrichment. It is affected by metamorphism that led to deformation of apatite nodules and formation of garnet porphyroblast inclusions. The role of Fe‐oxyhydroxides in element scavenging is highlighted by some apatite nodules that maintain their primary middle rare earth element enrichment, while others are characterized by altered rare earth element patterns resulting from competition for these elements between co‐crystallizing minerals during deformation. A systematic shift towards lower δ\n              18\n              O and radiogenic Sr isotopic composition compared to contemporaneous seawater indicate interaction with\n              18\n              O‐depleted meteoric fluids and a crustal component. By contrast, carbonate‐rich fluorapatite from the Late Cretaceous phosphatic chalk mostly keeps its primary trace element and isotopic signatures (close to seawater), although an external rare earth element addition is noted, as well as rare earth element redistribution induced by diagenetic alteration. Cenozoic carbonate fluorapatite nodules mostly present flat rare earth element patterns that are indicative of a detrital influence. Slight changes in rare earth element distribution are assigned to post‐depositional alteration, which also led to an increase in radiogenic Sr, with unchanged δ\n              18\n              O compared to seawater. The methodology followed here efficiently helps in deciphering the processes that modified the chemistry of apatite in the frame of major phosphogenic events.",
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            "title": "Novel extraction route of lithium from α-spodumene by dry chlorination",
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            "abstractNote": "Processing spodumene for lithium is challenging as it requires a high temperature transformation of the natural α-monoclinic form to β-tetragonal form, usually followed by acid baking and digestion.\n          , \n            \n              Processing spodumene for lithium is challenging as it requires a high temperature transformation of the natural α-monoclinic form to β-tetragonal form, usually followed by acid baking and digestion. This three-step extraction process requires significant heat energy, acid, process complexity and residence time, leading to both operating and capital costs. An approach which helps to eliminate this challenge will therefore be a milestone in processing spodumene. This study, thus, investigates a direct chlorination of α-spodumene using calcium chloride followed by water leaching of the residue to recover lithium, which reduces the energy requirement and number of unit operations. HSC Chemistry software was used to simulate the process using both phases (α and β) of the mineral up to 1100 °C prior to experimental investigation. The α-form was the only polymorph identified in residues after leaching, suggesting that the extraction is directly from the α-phase. However, an initial formation of a metastable β-form followed by a fast synthesis of lithium chloride from it is also suspected. Under optimal conditions of calcium chloride/spodumene molar ratio of 2.0, and 1000 °C treatment for 60 minutes, almost 90 percent lithium chloride was extracted and 85 percent was recovered to the leach solution with the remainder exiting with the off-gas. An apparent activation energy of about 122 ± 6 kJ mol\n              −1\n              was obtained at temperatures ranging from 800 to 950 °C during the process.",
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            "date": "2022",
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