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            "abstractNote": "We applied the Denitrification-Decomposition (DNDC) model to a typical corn–soybean rotation on silty clay loams with tile-drainage in east-central Illinois (IL). Model outcomes are compared to 10 years of observed drainage and nitrate leaching data aggregated across the Embarras River watershed. We found that accurate simulation of NO3–N leaching and drainage dynamics required significant changes to key soil physical and chemical parameters relative to their default values. Overall, our calibration of DNDC resulted in a good statistical fit between model output and IL data for crop yield, NO3–N leaching, and drainage. Our modifications to DNDC reduced the RMSE from 9.4 to a range of 1.3–2.9 for NO3–N leaching and from 51.2 to a range of 13–23.6 for drainage. Modeling efficiency ranged from 0.25 to 0.85 in comparison with measured drainage and leachate values and from 0.65 to 1 in comparison with crop yield data. However, analysis of simulation results at a monthly time step indicated that DNDC consistently underpredicted peak drainage events. Underprediction ranged from 50 to 100 mm month−1 following three extreme precipitation events, a flux equivalent to 0.25–0.5 of the total measured monthly flux. Our simulations demonstrated high interannual variation in nitrate leaching with average annual NO3–N loss of 24 kg N ha−1, peak annual NO3–N loss of 58 kg N ha−1 and low annual NO3–N loss of 1–5 kg N ha−1.",
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            "place": "",
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            "partNumber": "",
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            "pages": "51-63",
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            "abstractNote": "Background and aims Roots and mycorrhizas play an important role in not only plant nutrient acquisition, but also ecosystem nutrient cycling. Methods A field experiment was undertaken in which the role of arbuscular mycorrhizas (AM) in the growth and nutrient acquisition of tomato plants was investigated. A mycorrhiza defective mutant of tomato (Solanum lycopersicum L.) (named rmc) and its mycorrhizal wild type progenitor (named 76R) were used to control for the formation of AM. The role of roots and AM in soil N cycling was studied by injecting a 15N-labelled nitrate solution into surface soil at different distances from the 76R and rmc genotypes of tomato, or in plant free soil. The impacts of mycorrhizal and non-mycorrhizal root systems on soil greenhouse gas (CO2 and 14+15N2O and 15N2O) emissions, relative to root free soils, were also studied. Results The formation of AM significantly enhanced plant growth and nutrient acquisition, including interception of recently applied NO 3 − . Whereas roots caused a small but significant decrease in 15N2O emissions from soils at 23 h after labeling, compared to the root-free treatment, arbuscular mycorrhizal fungi (AMF) had little effect on N2O emissions. In contrast soil CO2 emissions were higher in plots containing mycorrhizal root systems, where root biomass was also greater. Conclusions Taken together, these data indicate that roots and AMF have an important role to play in plant nutrient acquisition and ecosystem N cycling.",
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            "abstractNote": "Nitrous oxide emissions were monitored at three sites over a 2-year period in irrigated cotton fields in Khorezm, Uzbekistan, a region located in the arid deserts of the Aral Sea Basin. The fields were managed using different fertilizer management strategies and irrigation water regimes. N2O emissions varied widely between years, within 1 year throughout the vegetation season, and between the sites. The amount of irrigation water applied, the amount and type of N fertilizer used, and topsoil temperature had the greatest effect on these emissions. Very high N2O emissions of up to 3000 μg N2O-N m−2 h−1 were measured in periods following N-fertilizer application in combination with irrigation events. These “emission pulses” accounted for 80–95% of the total N2O emissions between April and September and varied from 0.9 to 6.5 kg N2O-N ha−1.. Emission factors (EF), uncorrected for background emission, ranged from 0.4% to 2.6% of total N applied, corresponding to an average EF of 1.48% of applied N fertilizer lost as N2O-N. This is in line with the default global average value of 1.25% of applied N used in calculations of N2O emissions by the Intergovernmental Panel on Climate Change. During the emission pulses, which were triggered by high soil moisture and high availability of mineral N, a clear diurnal pattern of N2O emissions was observed, driven by daily changes in topsoil temperature. For these periods, air sampling from 8:00 to 10:00 and from 18:00 to 20:00 was found to best represent the mean daily N2O flux rates. The wet topsoil conditions caused by irrigation favored the production of N2O from NO3− fertilizers, but not from NH4+ fertilizers, thus indicating that denitrification was the main process causing N2O emissions. It is therefore argued that there is scope for reducing N2O emission from irrigated cotton production; i.e. through the exclusive use of NH4+ fertilizers. Advanced application and irrigation techniques such as subsurface fertilizer application, drip irrigation and fertigation may also minimize N2O emission from this regionally dominant agro-ecosystem.",
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            "title": "Nitrogen fertilizers promote denitrification",
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                    "firstName": "R. L.",
                    "lastName": "Mulvaney"
                },
                {
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                    "firstName": "S. A.",
                    "lastName": "Khan"
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            "abstractNote": "A laboratory study was conducted to compare the effects of different N fertilizers on emission of N2 and N2O during denitrification of NO3 – in waterlogged soil. Field-moist samples of Drummer silty clay loam soil (fine-silty, mixed, mesic Typic Haplaquoll) were incubated under aerobic conditions for 0, 2, 4, 7, 14, 21, or 42 days with or without addition of unlabelled (NH4)2SO4, urea, NH4H2PO4, (NH4)2HPO4, NH4NO3 (200 or 1000 mg N kg–1 soil), or liquid anhydrous NH3 (1000 mg N kg–1 soil). The incubated soil samples were then treated with 15N-labelled KNO3 (250 mg N kg–1 soil, 73.7 atom% 15N), and incubation was carried out under waterlogged conditions for 5 days, followed by collection of atmospheric samples for 15N analyses to determine labelled N2 and N2O. Compared to samples incubated without addition of unlabelled N, all of the fertilizers promoted denitrification of 15NO3 –. Emission of labelled N2 and N2O decreased in the order: Anhydrous NH3>urea<>\\gg<> (NH4)2HPO4>(NH4)2SO4≃NH4NO3≃NH4H2PO4. The highest emissions observed with anhydrous NH3 or urea coincided with the presence of NO2 –, and 15N analyses indicated that these emissions originated from NO2 – rather than NO3 –. Emissions of labelled N2 and N2O were significantly correlated with fertilizer effects on soil pH and water-soluble organic C.",
            "publicationTitle": "Biology and Fertility of Soils",
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            "pages": "211-220",
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            "journalAbbreviation": "Biol Fertil Soils",
            "DOI": "10.1007/s003740050233",
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                    "tag": "15N",
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                },
                {
                    "tag": "Fertilizer efficiency",
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                {
                    "tag": "Key words Denitrification",
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                {
                    "tag": "Labelled dinitrogen",
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                {
                    "tag": "Nitrification",
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                {
                    "tag": "Nitrous oxide",
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                {
                    "tag": "Urea",
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                {
                    "tag": "Water-soluble organic carbon",
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                {
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