[ { "key": "B2KEZAH7", "version": 1, "library": { "type": "group", "id": 11114, "name": "perrin", "links": { "alternate": { "href": "https://www.zotero.org/groups/perrin", "type": "text/html" } } }, "links": { "self": { "href": "https://api.zotero.org/groups/11114/items/B2KEZAH7", "type": "application/json" }, "alternate": { "href": "https://www.zotero.org/groups/perrin/items/B2KEZAH7", "type": "text/html" } }, "meta": { "createdByUser": { "id": 95100, "username": "perrin", "name": "Laurent PERRIN", "links": { "alternate": { "href": "https://www.zotero.org/perrin", "type": "text/html" } } }, "creatorSummary": "Callé et al.", "parsedDate": "2005", "numChildren": 0 }, "data": { "key": "B2KEZAH7", "version": 1, "itemType": "journalArticle", "title": "Influence of the size distribution and concentration on wood dust explosion: Experiments and reaction modelling", "creators": [ { "creatorType": "author", "firstName": "S.", "lastName": "Callé" }, { "creatorType": "author", "firstName": "L.", "lastName": "Klaba" }, { "creatorType": "author", "firstName": "D.", "lastName": "Thomas" }, { "creatorType": "author", "firstName": "L.", "lastName": "Perrin" }, { "creatorType": "author", "firstName": "O.", "lastName": "Dufaud" } ], "abstractNote": "The explosion ability of wood dust was characterized by a 20 L explosion sphere (Kühner). The overpressure inside the sphere is recorded during the explosion. The results show that the violence of the explosion is all the more important that the particle size is low. A model based on balances on chemical reaction, kinetics and thermodynamics leads to the representation of the pressure change during the explosion. There is a good agreement between the calculations and the experiments. © 2005 Elsevier B.V. All rights reserved.", "publicationTitle": "Powder Technology", "publisher": "", "place": "", "date": "2005", "volume": "157", "issue": "1-3", "section": "", "partNumber": "", "partTitle": "", "pages": "144-148", "series": "", "seriesTitle": "", "seriesText": "", "journalAbbreviation": "", "DOI": "", "citationKey": "", "url": "http://www.scopus.com/inward/record.url?eid=2-s2.0-26444571355&partnerID=40&md5=1031858b552d3a7fd5ca2c2720d9fa12", "accessDate": "2010-02-04T10:59:11Z", "PMID": "", "PMCID": "", "ISSN": "", "archive": "", "archiveLocation": "", "shortTitle": "Influence of the size distribution and concentration on wood dust explosion", "language": "", "libraryCatalog": "Scopus", "callNumber": "", "rights": "", "extra": "", "tags": [ { "tag": "Combustion", "type": 1 }, { "tag": "Dust", "type": 1 }, { "tag": "Explosion", "type": 1 }, { "tag": "Overpressure", "type": 1 } ], "collections": [ "VQRJWBCP" ], "relations": {}, "dateAdded": "2010-02-04T11:22:17Z", "dateModified": "2010-02-04T11:22:17Z" } }, { "key": "HMB4JAPA", "version": 1, "library": { "type": "group", "id": 11114, "name": "perrin", "links": { "alternate": { "href": "https://www.zotero.org/groups/perrin", "type": "text/html" } } }, "links": { "self": { "href": "https://api.zotero.org/groups/11114/items/HMB4JAPA", "type": "application/json" }, "alternate": { "href": "https://www.zotero.org/groups/perrin/items/HMB4JAPA", "type": "text/html" } }, "meta": { "createdByUser": { "id": 95100, "username": "perrin", "name": "Laurent PERRIN", "links": { "alternate": { "href": "https://www.zotero.org/perrin", "type": "text/html" } } }, "creatorSummary": "Dufaud et al.", "parsedDate": "2009", "numChildren": 0 }, "data": { "key": "HMB4JAPA", "version": 1, "itemType": "journalArticle", "title": "Explosions of vapour/dust hybrid mixtures: A particular class", "creators": [ { "creatorType": "author", "firstName": "O.", "lastName": "Dufaud" }, { "creatorType": "author", "firstName": "L.", "lastName": "Perrin" }, { "creatorType": "author", "firstName": "M.", "lastName": "Traore" }, { "creatorType": "author", "firstName": "S.", "lastName": "Chazelet" }, { "creatorType": "author", "firstName": "D.", "lastName": "Thomas" } ], "abstractNote": "The aim of this work is to demonstrate the particular aspects of the explosion of hybrid mixtures with respect to either vapour or dust explosions. This work is focused on pharmaceutical products from excipients to active drug substances and their associated solvents. Experiments with an explosion sphere has been used to determined the influence of dusts and vapours concentrations on the severity of explosions (maximum pressure Pmax and maximum rate of pressure rise (dP/dt)max). Results clearly show that the explosion behaviour of such hybrid mixtures reveals significant differences with respect to either vapour or dust explosions; especially a promotion effect on the combustion kinetics and on the rate of pressure rise for poor mixtures. The influences of the introduction of small amount of vapour on the minimum explosible dust concentration (MEC) and of dust addition on the lower explosion limit (LEL) are noteworthy. © 2008 Elsevier B.V. All rights reserved.", "publicationTitle": "Powder Technology", "publisher": "", "place": "", "date": "2009", "volume": "190", "issue": "1-2", "section": "", "partNumber": "", "partTitle": "", "pages": "269-273", "series": "", "seriesTitle": "", "seriesText": "", "journalAbbreviation": "", "DOI": "", "citationKey": "", "url": "http://www.scopus.com/inward/record.url?eid=2-s2.0-60249089894&partnerID=40&md5=5efff4db1a4e979b3dbef69800cd86ae", "accessDate": "2010-02-04T11:13:20Z", "PMID": "", "PMCID": "", "ISSN": "", "archive": "", "archiveLocation": "", "shortTitle": "Explosions of vapour/dust hybrid mixtures", "language": "", "libraryCatalog": "Scopus", "callNumber": "", "rights": "", "extra": "", "tags": [ { "tag": "Dust explosion", "type": 1 }, { "tag": "Explosion severity", "type": 1 }, { "tag": "Explosivity limits", "type": 1 }, { "tag": "Hybrid mixtures", "type": 1 }, { "tag": "Vapours", "type": 1 } ], "collections": [ "VQRJWBCP" ], "relations": {}, "dateAdded": "2010-02-04T11:22:17Z", "dateModified": "2010-02-04T11:22:17Z" } }, { "key": "NHVNVPMJ", "version": 1, "library": { "type": "group", "id": 11114, "name": "perrin", "links": { "alternate": { "href": "https://www.zotero.org/groups/perrin", "type": "text/html" } } }, "links": { "self": { "href": "https://api.zotero.org/groups/11114/items/NHVNVPMJ", "type": "application/json" }, "alternate": { "href": "https://www.zotero.org/groups/perrin/items/NHVNVPMJ", "type": "text/html" } }, "meta": { "createdByUser": { "id": 95100, "username": "perrin", "name": "Laurent PERRIN", "links": { "alternate": { "href": "https://www.zotero.org/perrin", "type": "text/html" } } }, "creatorSummary": "Traoré et al.", "parsedDate": "2009", "numChildren": 0 }, "data": { "key": "NHVNVPMJ", "version": 1, "itemType": "journalArticle", "title": "Dust explosions: How should the influence of humidity be taken into account?", "creators": [ { "creatorType": "author", "firstName": "M.", "lastName": "Traoré" }, { "creatorType": "author", "firstName": "O.", "lastName": "Dufaud" }, { "creatorType": "author", "firstName": "L.", "lastName": "Perrin" }, { "creatorType": "author", "firstName": "S.", "lastName": "Chazelet" }, { "creatorType": "author", "firstName": "D.", "lastName": "Thomas" } ], "abstractNote": "In this work, the influence of humidity on dust explosions of metallic (aluminium) and organic materials (icing sugar, polyethylene and magnesium stearate) has been studied. The impact of pre-humidification of powders on their ignition sensitivity, their volume resistivity and charge decay time has been assessed. The influence of humidity on explosion severity has also been studied by two methods: on the one hand, the dust sample was stored in a controlled workstation at constant relative humidity; on the other hand, the dry dust was dispersed in a humidity controlled atmosphere in the vessel. As expected, the effect of humidity strongly depends on the chemical nature of the particles. Experiments on powders volume resistivity and charge decay time have shown typical trends but have especially pointed out the inadequacy of some standards. Inhibition phenomena have been verified for polyethylene and magnesium stearate, whereas both inhibition and promotion have been observed for icing sugar and could be explained by an evolution of sucrose structure. Dry aluminium dust explosions in humid atmosphere show that water vapour inerts the explosion. However, when aluminium is stored at controlled humidity, the maximum rise of pressure rate increases with the water content, which is probably due to hydrogen generation. © 2008 The Institution of Chemical Engineers.", "publicationTitle": "Process Safety and Environmental Protection", "publisher": "", "place": "", "date": "2009", "volume": "87", "issue": "1", "section": "", "partNumber": "", "partTitle": "", "pages": "14-20", "series": "", "seriesTitle": "", "seriesText": "", "journalAbbreviation": "", "DOI": "", "citationKey": "", "url": "http://www.scopus.com/inward/record.url?eid=2-s2.0-58249090354&partnerID=40&md5=59ad0975502e8c2fd664cae64f10ceee", "accessDate": "2010-02-04T11:12:17Z", "PMID": "", "PMCID": "", "ISSN": "", "archive": "", "archiveLocation": "", "shortTitle": "Dust explosions", "language": "", "libraryCatalog": "Scopus", "callNumber": "", "rights": "", "extra": "", "tags": [ { "tag": "Dust explosions", "type": 1 }, { "tag": "Equilibrium relative humidity", "type": 1 }, { "tag": "Ignition sensitivity", "type": 1 }, { "tag": "Standards", "type": 1 }, { "tag": "Static electricity", "type": 1 } ], "collections": [ "VQRJWBCP" ], "relations": {}, "dateAdded": "2010-02-04T11:22:17Z", "dateModified": "2010-02-04T11:22:17Z" } }, { "key": "T4GDDUI4", "version": 1, "library": { "type": "group", "id": 11114, "name": "perrin", "links": { "alternate": { "href": "https://www.zotero.org/groups/perrin", "type": "text/html" } } }, "links": { "self": { "href": "https://api.zotero.org/groups/11114/items/T4GDDUI4", "type": "application/json" }, "alternate": { "href": "https://www.zotero.org/groups/perrin/items/T4GDDUI4", "type": "text/html" } }, "meta": { "createdByUser": { "id": 95100, "username": "perrin", "name": "Laurent PERRIN", "links": { "alternate": { "href": "https://www.zotero.org/perrin", "type": "text/html" } } }, "creatorSummary": "Bultel et al.", "parsedDate": "2007", "numChildren": 0 }, "data": { "key": "T4GDDUI4", "version": 1, "itemType": "journalArticle", "title": "Risk analysis on a fuel cell in electric vehicle using the MADS/MOSAR methodology", "creators": [ { "creatorType": "author", "firstName": "Y.", "lastName": "Bultel" }, { "creatorType": "author", "firstName": "M.", "lastName": "Aurousseau" }, { "creatorType": "author", "firstName": "P.", "lastName": "Ozil" }, { "creatorType": "author", "firstName": "L.", "lastName": "Perrin" } ], "abstractNote": "Fuel cells are processes of electric and thermal energy production which can be used for electric vehicles. They deliver strong power densities and do not require load time as batteries do. However, the use of fuel cells introduces strong constraints related to their different parts: feed systems, conversion and storage of fuel (hydrogen or methanol), management of the produced energy either under electric or thermal form, discharge of exhaust gases. The risk analysis presented in this paper consists of forecasting and minimizing undesired events that could occur when a fuel cell is powering an electric vehicle. This study refers to electric vehicles based on relevant fuel feeds (e.g., hydrogen or methanol). The MADS/MOSAR methodology is used. Five scenarios of accident are highlighted, leading to jet flame, BLEVE, internal combustion, unconfined explosion and environmental pollution. They are evaluated and prioritized by using Severity versus Probability grid. The main risk in terms of both severity and probability is related to fuel handling that can be nevertheless limited by using prevention and protection barriers. Due to the low durability of the electrolyte, the risk of electrolyte failure can be also very important. © 2007 Institution of Chemical Engineers.", "publicationTitle": "Process Safety and Environmental Protection", "publisher": "", "place": "", "date": "2007", "volume": "85", "issue": "3 B", "section": "", "partNumber": "", "partTitle": "", "pages": "241-250", "series": "", "seriesTitle": "", "seriesText": "", "journalAbbreviation": "", "DOI": "", "citationKey": "", "url": "http://www.scopus.com/inward/record.url?eid=2-s2.0-34249287934&partnerID=40&md5=9a1e145727e18e83c5083e3fdbe02b48", "accessDate": "2010-02-04T11:08:10Z", "PMID": "", "PMCID": "", "ISSN": "", "archive": "", "archiveLocation": "", "shortTitle": "", "language": "", "libraryCatalog": "Scopus", "callNumber": "", "rights": "", "extra": "", "tags": [ { "tag": "Fuel cell", "type": 1 }, { "tag": "Hydrogen", "type": 1 }, { "tag": "MADS/MOSAR methodology", "type": 1 }, { "tag": "Risk analysis", "type": 1 }, { "tag": "Systemic and deterministic approach", "type": 1 } ], "collections": [ "CZGUIWH3" ], "relations": {}, "dateAdded": "2010-02-04T11:21:08Z", "dateModified": "2010-02-04T11:21:08Z" } }, { "key": "4JU4NTRT", "version": 1, "library": { "type": "group", "id": 11114, "name": "perrin", "links": { "alternate": { "href": "https://www.zotero.org/groups/perrin", "type": "text/html" } } }, "links": { "self": { "href": "https://api.zotero.org/groups/11114/items/4JU4NTRT", "type": "application/json" }, "alternate": { "href": "https://www.zotero.org/groups/perrin/items/4JU4NTRT", "type": "text/html" } }, "meta": { "createdByUser": { "id": 95100, "username": "perrin", "name": "Laurent PERRIN", "links": { "alternate": { "href": "https://www.zotero.org/perrin", "type": "text/html" } } }, "creatorSummary": "Perrin and Laurent", "parsedDate": "2008", "numChildren": 0 }, "data": { "key": "4JU4NTRT", "version": 1, "itemType": "journalArticle", "title": "Current situation and future implementation of safety curricula for chemical engineering education in France", "creators": [ { "creatorType": "author", "firstName": "L", "lastName": "Perrin" }, { "creatorType": "author", "firstName": "A", "lastName": "Laurent" } ], "abstractNote": "", "publicationTitle": "Education for Chemical Engineers", "publisher": "", "place": "", "date": "12/2008", "volume": "3", "issue": "2", "section": "", "partNumber": "", "partTitle": "", "pages": "e84-e91", "series": "", "seriesTitle": "", "seriesText": "", "journalAbbreviation": "Education for Chemical Engineers", "DOI": "10.1016/j.ece.2008.08.001", "citationKey": "", "url": "http://linkinghub.elsevier.com/retrieve/pii/S1749772808000109", "accessDate": "", "PMID": "", "PMCID": "", "ISSN": "17497728", "archive": "", "archiveLocation": "", "shortTitle": "", "language": "", "libraryCatalog": "", "callNumber": "", "rights": "", "extra": "", "tags": [], "collections": [ "D7NNRII2" ], "relations": {}, "dateAdded": "2010-02-04T11:20:16Z", "dateModified": "2010-02-04T11:20:16Z" } }, { "key": "RTF824JD", "version": 1, "library": { "type": "group", "id": 11114, "name": "perrin", "links": { "alternate": { "href": "https://www.zotero.org/groups/perrin", "type": "text/html" } } }, "links": { "self": { "href": "https://api.zotero.org/groups/11114/items/RTF824JD", "type": "application/json" }, "alternate": { "href": "https://www.zotero.org/groups/perrin/items/RTF824JD", "type": "text/html" } }, "meta": { "createdByUser": { "id": 95100, "username": "perrin", "name": "Laurent PERRIN", "links": { "alternate": { "href": "https://www.zotero.org/perrin", "type": "text/html" } } }, "creatorSummary": "El Brihi et al.", "parsedDate": "2003", "numChildren": 0 }, "data": { "key": "RTF824JD", "version": 1, "itemType": "journalArticle", "title": "VOCs isotherms on day zeolite by static and dynamic methods: Experiments and modelling", "creators": [ { "creatorType": "author", "firstName": "T.", "lastName": "El Brihi" }, { "creatorType": "author", "firstName": "J.-N.", "lastName": "Jaubert" }, { "creatorType": "author", "firstName": "D.", "lastName": "Barth" }, { "creatorType": "author", "firstName": "L.", "lastName": "Perrin" } ], "abstractNote": "A dynamic method and a static gravimetric method are respectively used to measure the adsorption equilibria of m-xylene and n-butyl acetate on Wessalith® DAY zeolite F20. The equilibrium experiments are performed at different temperatures for both volatile organic compounds (VOCs). The m-xylene isotherms obtained in this study by the dynamic method are compared to our recently published data in which the static gravimetric method was used in order to test the influence of the experimental technique. Because the adsorption isotherms of m-xylene were correlated in our previous paper, in this study only the n-butyl acetate experimental data are correlated with various adsorption isotherm models: Langmuir, Toth and Dubinin equations.", "publicationTitle": "Environmental Technology", "publisher": "", "place": "", "date": "2003", "volume": "24", "issue": "10", "section": "", "partNumber": "", "partTitle": "", "pages": "1201-1210", "series": "", "seriesTitle": "", "seriesText": "", "journalAbbreviation": "", "DOI": "", "citationKey": "", "url": "http://www.scopus.com/inward/record.url?eid=2-s2.0-0344034361&partnerID=40&md5=60757012c254e549bf22fb8879083da4", "accessDate": "2010-02-04T10:58:15Z", "PMID": "", "PMCID": "", "ISSN": "", "archive": "", "archiveLocation": "", "shortTitle": "VOCs isotherms on day zeolite by static and dynamic methods", "language": "", "libraryCatalog": "Scopus", "callNumber": "", "rights": "", "extra": "", "tags": [ { "tag": "Adsorption", "type": 1 }, { "tag": "DAY zeolite", "type": 1 }, { "tag": "Dynamic method", "type": 1 }, { "tag": "Static method", "type": 1 }, { "tag": "VOC removal", "type": 1 } ], "collections": [ "VB2GIDIV" ], "relations": {}, "dateAdded": "2010-02-04T11:19:16Z", "dateModified": "2010-02-04T11:19:16Z" } }, { "key": "5F689A93", "version": 1, "library": { "type": "group", "id": 11114, "name": "perrin", "links": { "alternate": { "href": "https://www.zotero.org/groups/perrin", "type": "text/html" } } }, "links": { "self": { "href": "https://api.zotero.org/groups/11114/items/5F689A93", "type": "application/json" }, "alternate": { "href": "https://www.zotero.org/groups/perrin/items/5F689A93", "type": "text/html" } }, "meta": { "createdByUser": { "id": 95100, "username": "perrin", "name": "Laurent PERRIN", "links": { "alternate": { "href": "https://www.zotero.org/perrin", "type": "text/html" } } }, "creatorSummary": "Perrin et al.", "parsedDate": "1996", "numChildren": 0 }, "data": { "key": "5F689A93", "version": 1, "itemType": "journalArticle", "title": "Sorption and diffusion of solvent vapours in poly(vinylalcohol) membranes of different crystallinity degrees", "creators": [ { "creatorType": "author", "firstName": "Laurent", "lastName": "Perrin" }, { "creatorType": "author", "firstName": "Quang Trong", "lastName": "Nguyen" }, { "creatorType": "author", "firstName": "Robert", "lastName": "Clement" }, { "creatorType": "author", "firstName": "Jean", "lastName": "Neel" } ], "abstractNote": "Solvent sorption and diffusion are the key processes that control membrane performances in membrane processes. The sorption characteristic of water and ethanol vapours in poly(vinylalcohol) (PVA) membranes of different crystallinity degrees was measured by microgravimetry and the diffusion characteristic was calculated from the sorption kinetics at different water activities by curve fitting. The sorption isotherms for water vapour in membranes of 28, 37, 44 and 56% crystallinity degrees at 40°C obey the Flory equation based on the polymer lattice model. When the sorption extent was corrected by assuming that only the polymer amorphous phase is accessible to the penetrant, a unique Flory chi interaction parameter, 0.3, was obtained for all samples except for the 28% crystallinity sample. For the latter sample, the lower chi value (0.18) obtained can be explained by a change in the sorption behaviour of the original crystalline domains which may undergo partial destruction. The diffusion coefficient increases with the average water content in the membrane according to an exponential relationship characterized by a limit diffusion coefficient and a plasticization coefficient. The higher the crystallinity of the membrane, the lower the values of the limit diffusion coefficient and the plasticization coefficient. The ethanol sorption was also well described by the Flory-Huggins equation. The limit diffusion coefficient for water was two orders of magnitude larger than that for ethanol.", "publicationTitle": "Polymer International", "publisher": "", "place": "", "date": "1996", "volume": "39", "issue": "3", "section": "", "partNumber": "", "partTitle": "", "pages": "251-260", "series": "", "seriesTitle": "", "seriesText": "", "journalAbbreviation": "", "DOI": "10.1002/(SICI)1097-0126(199603)39:3<251::AID-PI496>3.0.CO;2-W", "citationKey": "", "url": "http://dx.doi.org/10.1002/(SICI)1097-0126(199603)39:3<251::AID-PI496>3.0.CO;2-W", "accessDate": "2010-02-04T10:35:53Z", "PMID": "", "PMCID": "", "ISSN": "", "archive": "", "archiveLocation": "", "shortTitle": "", "language": "", "libraryCatalog": "Wiley InterScience", "callNumber": "", "rights": "", "extra": "", "tags": [], "collections": [ "VB2GIDIV" ], "relations": {}, "dateAdded": "2010-02-04T11:19:16Z", "dateModified": "2010-02-04T11:19:16Z" } }, { "key": "2BU649MG", "version": 1, "library": { "type": "group", "id": 11114, "name": "perrin", "links": { "alternate": { "href": "https://www.zotero.org/groups/perrin", "type": "text/html" } } }, "links": { "self": { "href": "https://api.zotero.org/groups/11114/items/2BU649MG", "type": "application/json" }, "alternate": { "href": "https://www.zotero.org/groups/perrin/items/2BU649MG", "type": "text/html" } }, "meta": { "createdByUser": { "id": 95100, "username": "perrin", "name": "Laurent PERRIN", "links": { "alternate": { "href": "https://www.zotero.org/perrin", "type": "text/html" } } }, "creatorSummary": "Quellec et al.", "parsedDate": "1998", "numChildren": 0 }, "data": { "key": "2BU649MG", "version": 1, "itemType": "journalArticle", "title": "Protein encapsulation within polyethylene glycol-coated nanospheres. I. Physicochemical characterization", "creators": [ { "creatorType": "author", "firstName": "P.", "lastName": "Quellec" }, { "creatorType": "author", "firstName": "R.", "lastName": "Gref" }, { "creatorType": "author", "firstName": "L.", "lastName": "Perrin" }, { "creatorType": "author", "firstName": "E.", "lastName": "Dellacherie" }, { "creatorType": "author", "firstName": "F.", "lastName": "Sommer" }, { "creatorType": "author", "firstName": "J.M.", "lastName": "Verbavatz" }, { "creatorType": "author", "firstName": "M.J.", "lastName": "Alonso" } ], "abstractNote": "The development of injectable nanoparticulate 'stealth' carriers for protein delivery is a major challenge. We have shown the possibility of entrapping human serum albumin (HSA) in polyethylene glycol (PEG)-coated monodisperse biodegradable nanospheres with a mean diameter of about 200 nm, prepared from amphiphilic diblock PEG-polylactic acid (PLA) copolymers, with loadings up to 9% (w/w). Microscopic techniques and surface analysis studies enabled us to prove that the protein was well entrapped and not adsorbed onto the particle surface. Zeta potential and water uptake studies corroborated that part of the PEG chains are located in the nanosphere matrix. Water uptake in the nanospheres was related to their chemical composition, i.e., the respective wt% of PEG and PLA in the matrix, and not on their fabrication procedure. The hydrophilic PEG blocks absorbed up to 130% (w/w) water, whereas PLA absorbed only about 10% (w/w). However, the rate of swelling at the beginning of the process was related to the structure of the matrix, more particularly to the manner in which PEG was disposed at the surface. Furthermore, it was shown that the PEG 'brush' at the nanosphere surface drastically reduces HSA adsorption on the PEG-PLA nanospheres compared to the PLA ones.\nThe development of injectable nanoparticulate `stealth' carriers for protein delivery is a major challenge. We have shown the possibility of entrapping human serum albumin (HSA) in polyethylene glycol (PEG)-coated monodisperse biodegradable nanospheres with a mean diameter of about 200 nm, prepared from amphiphilic diblock PEG-polylactic acid (PLA) copolymers, with loadings up to 9% (w/w). Microscopic techniques and surface analysis studies enabled us to prove that the protein was well entrapped and not adsorbed onto the particle surface. Zeta potential and water uptake studies corroborated that part of the PEG chains are located in the nanosphere matrix. Water uptake in the nanospheres was related to their chemical composition, i.e., the respective wt% of PEG and PLA in the matrix, and not on their fabrication procedure. The hydrophilic PEG blocks absorbed up to 130% (w/w) water, whereas PLA absorbed only about 10% (w/w). However, the rate of swelling at the beginning of the process was related to the structure of the matrix, more particularly to the manner in which PEG was disposed at the surface. Furthermore, it was shown that the PEG `brush' at the nanosphere surface drastically reduces HSA adsorption on the PEG-PLA nanospheres compared to the PLA ones.", "publicationTitle": "Journal of Biomedical Materials Research", "publisher": "", "place": "", "date": "1998", "volume": "42", "issue": "1", "section": "", "partNumber": "", "partTitle": "", "pages": "45-54", "series": "", "seriesTitle": "", "seriesText": "", "journalAbbreviation": "", "DOI": "", "citationKey": "", "url": "http://www.scopus.com/inward/record.url?eid=2-s2.0-0032188874&partnerID=40&md5=6c5a2f786fba0cb6474321322d7ab270", "accessDate": "2010-02-04T10:45:08Z", "PMID": "", "PMCID": "", "ISSN": "", "archive": "", "archiveLocation": "", "shortTitle": "", "language": "", "libraryCatalog": "Scopus", "callNumber": "", "rights": "", "extra": "", "tags": [ { "tag": "Nanospheres", "type": 1 }, { "tag": "Polylactic acid-polyethylene glycol", "type": 1 }, { "tag": "Protein delivery", "type": 1 }, { "tag": "Protein encapsulation", "type": 1 } ], "collections": [ "VB2GIDIV" ], "relations": {}, "dateAdded": "2010-02-04T11:19:16Z", "dateModified": "2010-02-04T11:19:16Z" } }, { "key": "34U32WFU", "version": 1, "library": { "type": "group", "id": 11114, "name": "perrin", "links": { "alternate": { "href": "https://www.zotero.org/groups/perrin", "type": "text/html" } } }, "links": { "self": { "href": "https://api.zotero.org/groups/11114/items/34U32WFU", "type": "application/json" }, "alternate": { "href": "https://www.zotero.org/groups/perrin/items/34U32WFU", "type": "text/html" } }, "meta": { "createdByUser": { "id": 95100, "username": "perrin", "name": "Laurent PERRIN", "links": { "alternate": { "href": "https://www.zotero.org/perrin", "type": "text/html" } } }, "creatorSummary": "Touchal et al.", "parsedDate": "2006", "numChildren": 0 }, "data": { "key": "34U32WFU", "version": 1, "itemType": "journalArticle", "title": "Pervaporation properties of polypyrrolidinone-based membranes for EtOH/ ETBE mixtures separation", "creators": [ { "creatorType": "author", "firstName": "S.", "lastName": "Touchal" }, { "creatorType": "author", "firstName": "D.", "lastName": "Roizard" }, { "creatorType": "author", "firstName": "L.", "lastName": "Perrin" } ], "abstractNote": "The separation of ethanol/ethyl-tertiobutylether mixtures by pervaporation was studied with new membranes prepared from N-vinyl-pyrrolidinone (NVP) and N-[3-(trimethylamoniopropyl)]methacrylamidemethylsulfate) (TMA). The pervaporation results showed that highly EtOH selective membranes could be obtained from PVP blends and from pyrrolidinone-based crosslinked copolymers. The influences of the polymer blend composition and the role of the polymer microstructures on the membrane properties were investigated. Whatever the exact NVP/TMA composition used, the membranes strongly favored the pervaporation of ethanol. The ethanol selectivity was higher for the lower PVP/TMA ratio. On the one hand, these results were ascribed to the high pyrrolidinone residues content, which is responsible of the enhanced EtOH sorption affinity. The observed permeation selectivity was in agreement with the swelling data also recorded with the different polymers, showing higher affinity for ethanol with PVP-enriched materials compared with TMA ones. This is a direct consequence of the Lewis base feature of pyrrolidinone sites towards EtOH molecules. On the other hand, the TMA residues improved the overall stability and selectivity of the membranes thanks to crosslinking reactions, which were induced by thermal treatment. A close comparison made between polymer blend and copolymer pervaporation results helped to clarify the TMA role of the membrane transport properties. © 2006 Wiley Periodicals, Inc.", "publicationTitle": "Journal of Applied Polymer Science", "publisher": "", "place": "", "date": "2006", "volume": "99", "issue": "6", "section": "", "partNumber": "", "partTitle": "", "pages": "3622-3630", "series": "", "seriesTitle": "", "seriesText": "", "journalAbbreviation": "", "DOI": "", "citationKey": "", "url": "http://www.scopus.com/inward/record.url?eid=2-s2.0-33644541115&partnerID=40&md5=25e4b3a7b86a6b25d2f862c0be30779a", "accessDate": "2010-02-04T11:00:48Z", "PMID": "", "PMCID": "", "ISSN": "", "archive": "", "archiveLocation": "", "shortTitle": "", "language": "", "libraryCatalog": "Scopus", "callNumber": "", "rights": "", "extra": "", "tags": [ { "tag": "Blends", "type": 1 }, { "tag": "Copolymerization", "type": 1 }, { "tag": "Ionomers", "type": 1 }, { "tag": "Membranes", "type": 1 }, { "tag": "Separation techniques", "type": 1 } ], "collections": [ "VB2GIDIV" ], "relations": {}, "dateAdded": "2010-02-04T11:19:16Z", "dateModified": "2010-02-04T11:19:16Z" } }, { "key": "CK4HIRTE", "version": 1, "library": { "type": "group", "id": 11114, "name": "perrin", "links": { "alternate": { "href": "https://www.zotero.org/groups/perrin", "type": "text/html" } } }, "links": { "self": { "href": "https://api.zotero.org/groups/11114/items/CK4HIRTE", "type": "application/json" }, "alternate": { "href": "https://www.zotero.org/groups/perrin/items/CK4HIRTE", "type": "text/html" } }, "meta": { "createdByUser": { "id": 95100, "username": "perrin", "name": "Laurent PERRIN", "links": { "alternate": { "href": "https://www.zotero.org/perrin", "type": "text/html" } } }, "creatorSummary": "Marais et al.", "parsedDate": "2000", "numChildren": 0 }, "data": { "key": "CK4HIRTE", "version": 1, "itemType": "journalArticle", "title": "Permeametric and microgravimetric studies of sorption and diffusion of water vapor in an unsaturated polyester", "creators": [ { "creatorType": "author", "firstName": "S.", "lastName": "Marais" }, { "creatorType": "author", "firstName": "M.", "lastName": "Métayer" }, { "creatorType": "author", "firstName": "T.Q.", "lastName": "Nguyen" }, { "creatorType": "author", "firstName": "M.", "lastName": "Labbé" }, { "creatorType": "author", "firstName": "L.", "lastName": "Perrin" }, { "creatorType": "author", "firstName": "J.M.", "lastName": "Saiter" } ], "abstractNote": "A detailed analysis of the sorption equilibrium and the diffusion of water vapor under different activities through an unsaturated polyester resin (UPR) has been undertaken by differential permeation and microgravimetry techniques. The BET-type III sorption isotherm obtained by microgravimetry was analyzed with the Zimm-Lundberg approach to determine the mean cluster size in the UPR film: the latter increases drastically with the water content in the film. The transient permeation flux can be well fitted when a concentration-dependent diffusivity of exponential type is used. From the water content at sorption equilibrium and the steady-state permeability, a mean diffusion coefficient for the steady state can be determined; its decrease with increasing water activity is consistent with the increase in the mean cluster size.\nA detailed analysis of the sorption equilibrium and the diffusion of water vapor under different activities through an unsaturated polyester resin (UPR) has been undertaken by differential permeation and microgravimetry techniques. The BET-type III sorption isotherm obtained by microgravimetry was analyzed with the Zimm-Lundberg approach to determine the mean cluster size in the UPR film: the latter increases drastically with the water content in the film. The transient permeation flux can be well fitted when a concentration-dependent diffusivity of exponential type is used. From the water content at sorption equilibrium and the steady-state permeability, a mean diffusion coefficient for the steady state can be determined; its decrease with increasing water activity is consistent with the increase in the mean cluster size.", "publicationTitle": "Polymer", "publisher": "", "place": "", "date": "2000", "volume": "41", "issue": "7", "section": "", "partNumber": "", "partTitle": "", "pages": "2667-2676", "series": "", "seriesTitle": "", "seriesText": "", "journalAbbreviation": "", "DOI": "", "citationKey": "", "url": "http://www.scopus.com/inward/record.url?eid=2-s2.0-17544393726&partnerID=40&md5=1d3e0d58f7c298b82fd78e0738effa18", "accessDate": "2010-02-04T10:52:50Z", "PMID": "", "PMCID": "", "ISSN": "", "archive": "", "archiveLocation": "", "shortTitle": "", "language": "", "libraryCatalog": "Scopus", "callNumber": "", "rights": "", "extra": "", "tags": [ { "tag": "Sorption isotherm", "type": 1 }, { "tag": "Unsaturated polyester", "type": 1 }, { "tag": "Water vapor", "type": 1 } ], "collections": [ "VB2GIDIV" ], "relations": {}, "dateAdded": "2010-02-04T11:19:16Z", "dateModified": "2010-02-04T11:19:16Z" } }, { "key": "55KI2F8G", "version": 1, "library": { "type": "group", "id": 11114, "name": "perrin", "links": { "alternate": { "href": "https://www.zotero.org/groups/perrin", "type": "text/html" } } }, "links": { "self": { "href": "https://api.zotero.org/groups/11114/items/55KI2F8G", "type": "application/json" }, "alternate": { "href": "https://www.zotero.org/groups/perrin/items/55KI2F8G", "type": "text/html" } }, "meta": { "createdByUser": { "id": 95100, "username": "perrin", "name": "Laurent PERRIN", "links": { "alternate": { "href": "https://www.zotero.org/perrin", "type": "text/html" } } }, "creatorSummary": "Jonquières et al.", "parsedDate": "1998", "numChildren": 0 }, "data": { "key": "55KI2F8G", "version": 1, "itemType": "journalArticle", "title": "Modelling of vapour sorption in polar materials: Comparison of Flory-Huggins and related models with the ENSIC mechanistic approach", "creators": [ { "creatorType": "author", "firstName": "A.", "lastName": "Jonquières" }, { "creatorType": "author", "firstName": "L.", "lastName": "Perrin" }, { "creatorType": "author", "firstName": "A.", "lastName": "Durand" }, { "creatorType": "author", "firstName": "S.", "lastName": "Arnold" }, { "creatorType": "author", "firstName": "P.", "lastName": "Lochon" } ], "abstractNote": "This work focuses on the analysis of organic vapour sorption in polymer systems strongly deviating from ideality. The sorption of three different types of organics (i.e. alcohol, ether, ester) in polyurethaneimide block copolymers has been investigated using a microgravimetric technique over the entire activity range. For all the polyurethaneimides, sorption increases in the following order: ETBE < EtOH < AcOEt. A further analysis in terms of the Flory-Huggins (FH) theory generally shows a great discrepancy between experimental and calculated sorption values. This quasi-systematic failure could be ascribed to a fairly strong dependence of FH interaction parameter χ towards penetrant concentration, which cannot be accounted for by the FH theory. A theoretical modification of the FH theory, previously reported by Koningsveld and Kleintjens to account for the variation by a three-parameter law, was shown to be really efficient for sorption modeling over the entire activity range. Despite a systematic divergence for the very low sorption levels, an empirical modification of the FH theory using a power law χ = α∅b could also be an interesting alternative which requires only two parameters for a fairly good modeling for activities higher than 0.1-0.2. Considering the sorption phenomenon as a mechanical anisotropic process,the recent ENSIC approach, reported by Favre et al., proved its striking efficiency allowing the sorption modelling of all the sorption isotherms with a mean correlation coefficient R = 0.9983.\nThis work focuses on the analysis of organic vapour sorption in polymer systems strongly deviating from ideality. The sorption of three different types of organics (i.e. alcohol, ether, ester) in polyurethaneimide block copolymers has been investigated using a microgravimetric technique over the entire activity range. For all the polyurethaneimides, sorption increases in the following order: ETBE3.0.CO;2-A", "citationKey": "", "url": "http://dx.doi.org/10.1002/(SICI)1097-0126(199701)42:1<9::AID-PI637>3.0.CO;2-A", "accessDate": "2010-02-04T10:38:07Z", "PMID": "", "PMCID": "", "ISSN": "", "archive": "", "archiveLocation": "", "shortTitle": "", "language": "", "libraryCatalog": "Wiley InterScience", "callNumber": "", "rights": "", "extra": "", "tags": [], "collections": [ "VB2GIDIV" ], "relations": {}, "dateAdded": "2010-02-04T10:38:55Z", "dateModified": "2010-02-04T10:38:55Z" } }, { "key": "68R89XQC", "version": 1, "library": { "type": "group", "id": 11114, "name": "perrin", "links": { "alternate": { "href": "https://www.zotero.org/groups/perrin", "type": "text/html" } } }, "links": { "self": { "href": "https://api.zotero.org/groups/11114/items/68R89XQC", "type": "application/json" }, "alternate": { "href": "https://www.zotero.org/groups/perrin/items/68R89XQC", "type": "text/html" } }, "meta": { "createdByUser": { "id": 95100, "username": "perrin", "name": "Laurent PERRIN", "links": { "alternate": { "href": "https://www.zotero.org/perrin", "type": "text/html" } } }, "creatorSummary": "Dufaud et al.", "parsedDate": "2008", "numChildren": 0 }, "data": { "key": "68R89XQC", "version": 1, "itemType": "journalArticle", "title": "Dust/vapour explosions: Hybrid behaviours?", "creators": [ { "creatorType": "author", "firstName": "O", "lastName": "Dufaud" }, { "creatorType": "author", "firstName": "L", "lastName": "Perrin" }, { "creatorType": "author", "firstName": "M", "lastName": "Traore" } ], "abstractNote": "", "publicationTitle": "Journal of Loss Prevention in the Process Industries", "publisher": "", "place": "", "date": "07/2008", "volume": "21", "issue": "4", "section": "", "partNumber": "", "partTitle": "", "pages": "481-484", "series": "", "seriesTitle": "", "seriesText": "", "journalAbbreviation": "Journal of Loss Prevention in the Process Industries", "DOI": "10.1016/j.jlp.2007.11.005", "citationKey": "", "url": "http://linkinghub.elsevier.com/retrieve/pii/S0950423007001416", "accessDate": "", "PMID": "", "PMCID": "", "ISSN": "09504230", "archive": "", "archiveLocation": "", "shortTitle": "", "language": "", "libraryCatalog": "", "callNumber": "", "rights": "", "extra": "", "tags": [], "collections": [ "VQRJWBCP" ], "relations": {}, "dateAdded": "2010-02-03T23:24:02Z", "dateModified": "2010-02-03T23:24:02Z" } }, { "key": "WTAXTSME", "version": 1, "library": { "type": "group", "id": 11114, "name": "perrin", "links": { "alternate": { "href": "https://www.zotero.org/groups/perrin", "type": "text/html" } } }, "links": { "self": { "href": "https://api.zotero.org/groups/11114/items/WTAXTSME", "type": "application/json" }, "alternate": { "href": "https://www.zotero.org/groups/perrin/items/WTAXTSME", "type": "text/html" } }, "meta": { "createdByUser": { "id": 95100, "username": "perrin", "name": "Laurent PERRIN", "links": { "alternate": { "href": "https://www.zotero.org/perrin", "type": "text/html" } } }, "creatorSummary": "Perrin et al.", "parsedDate": "2007", "numChildren": 0 }, "data": { "key": "WTAXTSME", "version": 1, "itemType": "journalArticle", "title": "Dust and electrostatic hazards, could we improve the current standards?", "creators": [ { "creatorType": "author", "firstName": "L", "lastName": "Perrin" }, { "creatorType": "author", "firstName": "A", "lastName": "Laurent" }, { "creatorType": "author", "firstName": "V", "lastName": "Falk" }, { "creatorType": "author", "firstName": "O", "lastName": "Dufaud" }, { "creatorType": "author", "firstName": "M", "lastName": "Traore" } ], "abstractNote": "", "publicationTitle": "Journal of Loss Prevention in the Process Industries", "publisher": "", "place": "", "date": "05/2007", "volume": "20", "issue": "3", "section": "", "partNumber": "", "partTitle": "", "pages": "207-217", "series": "", "seriesTitle": "", "seriesText": "", "journalAbbreviation": "Journal of Loss Prevention in the Process Industries", "DOI": "10.1016/j.jlp.2007.03.006", "citationKey": "", "url": "http://linkinghub.elsevier.com/retrieve/pii/S0950423007000125", "accessDate": "", "PMID": "", "PMCID": "", "ISSN": "09504230", "archive": "", "archiveLocation": "", "shortTitle": "", "language": "", "libraryCatalog": "", "callNumber": "", "rights": "", "extra": "", "tags": [], "collections": [ "VQRJWBCP" ], "relations": {}, "dateAdded": "2010-02-03T23:24:02Z", "dateModified": "2010-02-03T23:24:02Z" } }, { "key": "MC6Z3IF3", "version": 1, "library": { "type": "group", "id": 11114, "name": "perrin", "links": { "alternate": { "href": "https://www.zotero.org/groups/perrin", "type": "text/html" } } }, "links": { "self": { "href": "https://api.zotero.org/groups/11114/items/MC6Z3IF3", "type": "application/json" }, "alternate": { "href": "https://www.zotero.org/groups/perrin/items/MC6Z3IF3", "type": "text/html" } }, "meta": { "createdByUser": { "id": 95100, "username": "perrin", "name": "Laurent PERRIN", "links": { "alternate": { "href": "https://www.zotero.org/perrin", "type": "text/html" } } }, "creatorSummary": "Sklet", "parsedDate": "2006", "numChildren": 0 }, "data": { "key": "MC6Z3IF3", "version": 1, "itemType": "journalArticle", "title": "Safety barriers: Definition, classification, and performance", "creators": [ { "creatorType": "author", "firstName": "S", "lastName": "Sklet" } ], "abstractNote": "", "publicationTitle": "Journal of Loss Prevention in the Process Industries", "publisher": "", "place": "", "date": "09/2006", "volume": "19", "issue": "5", "section": "", "partNumber": "", "partTitle": "", "pages": "494-506", "series": "", "seriesTitle": "", "seriesText": "", "journalAbbreviation": "Journal of Loss Prevention in the Process Industries", "DOI": "10.1016/j.jlp.2005.12.004", "citationKey": "", "url": "http://linkinghub.elsevier.com/retrieve/pii/S0950423005001968", "accessDate": "", "PMID": "", "PMCID": "", "ISSN": "09504230", "archive": "", "archiveLocation": "", "shortTitle": "", "language": "", "libraryCatalog": "", "callNumber": "", "rights": "", "extra": "", "tags": [], "collections": [ "CZGUIWH3", "U6G458FH" ], "relations": {}, "dateAdded": "2010-02-03T23:23:40Z", "dateModified": "2010-02-03T23:23:40Z" } }, { "key": "QW32NTJC", "version": 1, "library": { "type": "group", "id": 11114, "name": "perrin", "links": { "alternate": { "href": "https://www.zotero.org/groups/perrin", "type": "text/html" } } }, "links": { "self": { "href": "https://api.zotero.org/groups/11114/items/QW32NTJC", "type": "application/json" }, "alternate": { "href": "https://www.zotero.org/groups/perrin/items/QW32NTJC", "type": "text/html" } }, "meta": { "createdByUser": { "id": 95100, "username": "perrin", "name": "Laurent PERRIN", "links": { "alternate": { "href": "https://www.zotero.org/perrin", "type": "text/html" } } }, "creatorSummary": "Schupp et al.", "parsedDate": "2006", "numChildren": 0 }, "data": { "key": "QW32NTJC", "version": 1, "itemType": "journalArticle", "title": "Design support for the systematic integration of risk reduction into early chemical process design", "creators": [ { "creatorType": "author", "firstName": "B", "lastName": "Schupp" }, { "creatorType": "author", "firstName": "A", "lastName": "Hale" }, { "creatorType": "author", "firstName": "H", "lastName": "Pasman" }, { "creatorType": "author", "firstName": "S", "lastName": "Lemkovitz" }, { "creatorType": "author", "firstName": "L", "lastName": "Goossens" } ], "abstractNote": "", "publicationTitle": "Safety Science", "publisher": "", "place": "", "date": "01/2006", "volume": "44", "issue": "1", "section": "", "partNumber": "", "partTitle": "", "pages": "37-54", "series": "", "seriesTitle": "", "seriesText": "", "journalAbbreviation": "Safety Science", "DOI": "10.1016/j.ssci.2005.09.002", "citationKey": "", "url": "http://linkinghub.elsevier.com/retrieve/pii/S0925753505000962", "accessDate": "", "PMID": "", "PMCID": "", "ISSN": "09257535", "archive": "", "archiveLocation": "", "shortTitle": "", "language": "", "libraryCatalog": "", "callNumber": "", "rights": "", "extra": "", "tags": [], "collections": [ "CZGUIWH3", "U6G458FH" ], "relations": {}, "dateAdded": "2010-02-03T23:23:40Z", "dateModified": "2010-02-03T23:23:40Z" } }, { "key": "A6DWQ33V", "version": 1, "library": { "type": "group", "id": 11114, "name": "perrin", "links": { "alternate": { "href": "https://www.zotero.org/groups/perrin", "type": "text/html" } } }, "links": { "self": { "href": "https://api.zotero.org/groups/11114/items/A6DWQ33V", "type": "application/json" }, "alternate": { "href": "https://www.zotero.org/groups/perrin/items/A6DWQ33V", "type": "text/html" } }, "meta": { "createdByUser": { "id": 95100, "username": "perrin", "name": "Laurent PERRIN", "links": { "alternate": { "href": "https://www.zotero.org/perrin", "type": "text/html" } } }, "creatorSummary": "Kletz", "parsedDate": "2003", "numChildren": 0 }, "data": { "key": "A6DWQ33V", "version": 1, "itemType": "journalArticle", "title": "Inherently Safer Design—Its Scope and Future", "creators": [ { "creatorType": "author", "firstName": "T", "lastName": "Kletz" } ], "abstractNote": "", "publicationTitle": "Process Safety and Environmental Protection", "publisher": "", "place": "", "date": "11/2003", "volume": "81", "issue": "6", "section": "", "partNumber": "", "partTitle": "", "pages": "401-405", "series": "", "seriesTitle": "", "seriesText": "", "journalAbbreviation": "Process Safety and Environmental Protection", "DOI": "10.1205/095758203770866566", "citationKey": "", "url": "http://linkinghub.elsevier.com/retrieve/pii/S0957582003711173", "accessDate": "", "PMID": "", "PMCID": "", "ISSN": "09575820", "archive": "", "archiveLocation": "", "shortTitle": "", "language": "", "libraryCatalog": "", "callNumber": "", "rights": "", "extra": "", "tags": [], "collections": [ "CZGUIWH3", "U6G458FH" ], "relations": {}, "dateAdded": "2010-02-03T23:23:40Z", "dateModified": "2010-02-03T23:23:40Z" } }, { "key": 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