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            "title": "Characterizing waste rock using automated quantitative electron microscopy",
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                    "firstName": "Randy J.",
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            "abstractNote": "The leaching of metals from waste rock is directly related to the mineralogical composition of the rock. The overall study objective was to evaluate the application of automated quantitative electron microscopy to weathering waste rock. The value of mineral liberation analysis in optimizing mineral processing operations has been well documented. Application of automated mineralogical techniques, such as the Mineral Liberation Analyzer, to environmental studies is less common with no waste rock characterization studies found that specifically use the Mineral Liberation Analyzer. Mineral Liberation Analyzer methodology limitations and advantages were explored in the context of detection and quantification of primary and secondary metal-associated mineral phases. Mineral Liberation Analyzer application to waste rock weathering studies was assessed using laboratory, field cell, and experimental pile samples which were separated into particle-size fractions. Mineral Liberation Analyzer characterization included bulk modal and metal-associated mineralogy, size distribution, and mineral liberation, association, and exposure or availability (to weathering processes) and mineralogical features useful to an environmental modeller. The Mineral Liberation Analyzer consisted of a FEI Quanta 600 scanning electron microscope equipped with dual Bruker-AXS silicon drift detectors, tungsten filament and proprietary software. The Mineral Liberation Analyzer demonstrated characterization of Antamina mine waste rock which would aid the understanding of weathering processes at this and other sites, such as tailings and heap leach activity. Important mineralogical and elemental features determined were: availability / exposure, particle / grain size and shape, association (such as locking and potential mineral-mineral interactions), quantity and type (such as crystal structure reactivity), fractures and porosity. The scope of this study does not extend to linking lithology to secondary mineralogy. The Mineral Liberation Analyzer, in conjunction with geochemistry, particle surface analysis tools, chemical speciation modeling and diagnostic sequential leach can advance waste rock characterization, to improve mitigation strategies for waste rock drainage.",
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            "title": "Automated Mineral Analysis of Mine Waste",
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                    "firstName": "Martha",
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            "abstractNote": "Mineral Liberation Analyzer (MLA) is an automated mineralogical system originally developed to characterize ore and mill feeds for the metallurgical processing industry. Its ability to quantitatively characterize solid and particulate material, including whole rock thin sections, waste rock, tailings, soil, and sediments, has led to increasing applications in other industries. The software uses back-scatter electron imagery and energy dispersive X-ray analysis to analyze each particle’s shape, size, and mineralogical information. Energy dispersive X-ray data are compared to a user-generated Mineral Reference Library consisting of known phases and corresponding EDS spectra to classify each particle. MLA is used in this study to provide quantitative assessments of mining-related environmental samples to answer questions regarding mineralogical controls on bioaccessibility, metal leaching/acid rock drainage potential, and anthropogenic influence. Six tailings samples from the New Calumet Mine in Quebec, Canada, were analyzed using MLA. Gastric Pb bioaccessibility testing and total metal content performed on these samples indicated that Pb bioaccessibility in the <250 micron size fraction was not directly correlated with the total Pb concentration. This suggested that there were mineralogical and/or physical controls on bioaccessibility. MLA was used to quantify the relative proportions of cerussite, a highly bioaccessible Pb carbonate, and galena, a lower bioaccessibility Pb sulfide. Liberation and particle size were also analyzed as controls on bioaccessibility. Sample GD-VEG1 (highest bioaccessibility) has the highest ratio of cerussite to galena, the smallest particle size, and the most liberated Pb-bearing particles. The New Calumet tailings were also analyzed using static testing, a suite of laboratory tests used by environmental scientists and mine operators to operationally define acid rock drainage and metal leaching potential. Modal mineralogy obtained from MLA analysis was used to calculate neutralization potential (NP) and acid potential (AP), taking into account the presence of iron carbonate minerals and iron-bearing sulfides other than pyrite. Results are within several units of those obtained by static testing. Two Ni-impacted soil samples collected from the region of Kalgoorlie, Australia were characterized using MLA. Previous studies had focused on bioaccessibility and sequential extraction testing and minor mineralogical work. Preliminary XANES characterization conflicted with mineralogy predicted from sequential extraction and EMPA and MLA were used to quantitatively characterize major Ni-bearing phases and resolve previous discrepancies.",
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            "itemType": "thesis",
            "title": "Geometallurgical Evaluation of the Nkout (Cameroon) and Putu (Liberia) Iron Ore Deposits",
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                {
                    "creatorType": "author",
                    "firstName": "Kelvin Frederick Esebewa",
                    "lastName": "Anderson"
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            "abstractNote": "The Nkout (Cameroon) and Putu (Liberia) oxide facies iron ore deposits comprise fresh magnetite banded iron formation (BIF) at depth, which weathers towards the surface, forming high grade martite–goethite ores. This study aimed to improve the mineralogical understanding of these deposits in order to predict their metallurgical responses. It concentrated on developing the QEMSCAN® technique and testing its application to these ore types, but also used a variety of other analysis methods. The QEMSCAN® species identification protocol was developed to include three goethite entries: goethite/limonite, phosphorus-bearing and aluminium-bearing goethite. QEMSCAN® was also used to distinguish between the iron oxides using their backscattered electron signals. To test the correlation between the mineralogy and metallurgical characteristics, magnetic separations were carried out. The samples were divided into 4 main groups based on their whole rock Fe content, determined by XRF analysis, and their degree of weathering: enriched material, weathered magnetite itabirite, transitional magnetite itabirite and magnetite itabirite. Quartz and Al oxide and hydroxide minerals such as gibbsite are the major gangue minerals in the magnetite BIF and martite–goethite ores respectively. From the QEMSCAN® analysis it was concluded that the iron oxides are closely associated and liberation of them individually is poor. Liberation increases when they are grouped together as iron oxide. Chamosite concentrations > 6 wt. % significantly lower liberation of the iron oxides. From the metallurgical testing, it was concluded that iron oxide modal mineralogy gives an indication of iron recovery but other QEMSCAN® data such as mineral association and liberation could be important especially if the iron oxide minerals are not liberated. Grain size and instrument characteristics also affect recovery of iron minerals. There is no evidence to show that there is any structural control on the BIF mineralisation at Nkout because metamorphism has significantly affected the lithological characteristics. The BIF mineralised zones occur as stacks with no particular stratigraphic relationship. Alteration and stratigraphy are the main controls on the martite–goethite ores. These results are applicable to most other BIFs so that as direct shipping ores are exhausted, the approach used here can help to develop the lower grade portions of the deposits.",
            "thesisType": "PhD Thesis",
            "university": "University of Exeter",
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            "date": "2014",
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            "extra": "This item is under Embargo until: 2015-12-16",
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            "title": "Applying image analysis to process control - from blasting to flotation.",
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                    "firstName": "R.D.",
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            "abstractNote": "The ever-increasing power (and decreasing cost) of computers has opened up substantial oppor¬tunities for 'Vision'-based systems in both on-line and off-line control. This paper reviews image analysis applications in use at the Julius Kruttschnitt Mineral Research Centre (JKMRC) for: •blast and mill feed size monitoring; •AG/SAG mill model-based control; •mineral liberation; and •froth flotation control. The SPLIT™ image analysis system is being used to estimate muck pile and ROM feed sizings. AG/SAG mill feed sizing is being used in a dynamic model for mill control. A new generation mineral liberation analyzer has been developed with Philips Electron Optics. The Philips-JKMRC mineral liberation analyzer offers a substantial improvement in resolution and speed over previous developments. While on-line liberation control continues to be something of a pipe dream, measuring liberation \"one shift behind\" is now feasible. A robust instrument has been developed to measure flotation froth bubble size and velocity. The instrument also derives a parameter that allows different froth textures to be distinguished. The instrument has been used for on-line control in coal and sulfide flotation. For coal froth, an online ash estimate has been achieved at one site and is being tested at other sites. Overall, image analysis is finding many applications in mineral processing and control.",
            "proceedingsTitle": "Control 2000 - Mineral and Metallurgical Processing",
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            "abstractNote": "The computerized scanning electron microscope system (QEM*SEM) as developed for characterizing whole mineral particles by the CSIRO Division of Mineral Chemistry, Institute of Energy and Earth Resources, has proved to be a very useful tool in the analysis of products and intermediate samples in the Lead-Zinc Concentrator of Mount Isa Mines Limited. Two examples of the application of the method are given in the present paper.\n\nThe analysis of final cleaner concentrates from two distinct ore blends has indicated that in each case most of the galena in the 10–37μm size range is fully or nearly fully liberated. This proportion decreased down the third cleaner cell bank.\n\nCoarser particles, in the 37–53μm size range, were shown to have smaller proportions of galena in the highly liberated galena classes.\n\nThe remainder of the galena in each case is spread over the lower galena classes, which become increasingly interlocked with gangue.\n\nSignificant proportions of gangue, both sulphide and non-sulphide were also found to be free or almost free from interlocking with galena, especially in the 10–37μm size fraction. Thus lack of selectivity, as well as composite particle flotation, is seen to be responsible for downgrading of lead third cleaner concentrates.\n\nIn addition, the QEM*SEM technique has shown that the distribution of galena intergrowth in lead first cleaner tailings is spread over most composite classes, more akin to regrind/retreat particles than to lead primary rougher tail particles.\n\nThus QEM*SEM provides a valuable method in the mineral industry of today of measuring the relative degree of liberation of ground ore or flotation products, and the extent of dilution of concentrates by non-selective flotation of liberated gangue. Full liberation is not always desirable because of the cost of grinding to the finest sizes and because non-selective dilution of concentrates by fine liberated gangue often increases. QEM*SEM can also play a useful role in deciding the best destination for intermediate concentrator streams.",
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            "abstractNote": "\"Waste is wasted if you waste it, otherwise it is a resource. Resource is wasted if you ignore it and do not conserve it with holistic best practices and reduce societal costs. Resource is for the transformation of people and society.\"1 Red mud is a worldwide problem with reserves in the hundreds of millions of tons and tens of millions of tons being added annually. Currently there is not an effective way to deal with this byproduct of the Bayer Process, the primary means of refining bauxite ore in order to provide alumina. This alumina is then treated by electrolysis using the Hall-Héroult process to produce elemental aluminum. The resulting mud is a mixture of solid and metallic oxides, and has proven to be a great disposal problem. This disposal problem is compounded by the fact that the typical bauxite processing plant produces up to three times as much red mud as alumina. Current practice of disposal is to store red mud in retention ponds until an economical fix can be discovered. The danger associated with this current method of storage is immense to the surrounding communities and environment, thus the interest from the Center for Resource Recovery and Recycling (CR3). The purpose of this document is to explain one way to remove the value added materials, primarily iron, from the Jamaican red mud using both pyrometallurgical and hydrometallurgical approaches. In the beginning, soda ash and carbon roasting were completed simultaneously at 800°C. This type of roasting produced results that were unacceptable. After the soda ash roast was completed independently of carbon roasting, a water wash produced results that separations of alumina at 90%, Iron at 99%, calcium at 99%, titanium t 100%, and sodium by 74%. Smelting produced separations of 97% for alumina, 99% for iron, 87% for sodium, 94% for calcium and 72% for titanium.",
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            "abstractNote": "The compositional distribution of a population of particles is often referred to as the liberation spectrum. The challenge is to sensibly represent the vast amount of information contained in the liberation spectrum in a format that can be interpreted in a processing context. This paper describes one approach that can be used to represent the liberation spectrum, from compositional data obtained from automated SEM-based systems, and discusses how ore characteristics, such as mineral grade and grain size and distribution, can be interpreted. Ores from five different locations are compared using pyrite as the mineral of interest to demonstrate the approach. How this data might be used in a mineral processing context is also discussed, specifically with reference to how this approach may be used to determine grinding targets for separation processes.",
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                    "firstName": "M",
                    "lastName": "Sciortino"
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            "abstractNote": "The Dumont deposit is a large (1179 Mt reserve), low-grade (0.27 per cent nickel) nickel sulfide project located in the Abitibi region 25 km west of Amos, Quebec. Royal Nickel Corporation (RNC)acquired the project in 2007 and has since taken the deposit through to feasibility. The disseminated nickel sulfide and alloy mineralisation is hosted within the serpentinised dunite subzone of the Dumont Sill; a differentiated, pervasively serpentinised, ultramafic sill of komatiitic affinity. Pentlandite ((Ni,Fe)9S8), heazlewoodite (Ni3S2) and awaruite (Ni2.5Fe) are the dominant nickel-bearing metallic phases and can be recovered by conventional methods (flotation, magnetic separation).\nNon-recoverable nickel is also present within serpentine and olivine of the silicate matrix. A detailed mineralogical program including 1420 QEMSCAN® samples and 4400 electron\nmicroprobe points was undertaken to increase the understanding of the nickel deportment in the various recoverable and non-recoverable phases in a spatial context across the deposit. A total\nof 105 metallurgical tests have been performed under a standard procedure which have linked the mineralogy to metallurgical performance. This has allowed the creation and modelling\nof geometallurgical domains on a block-by-block basis to understand the recovery variation and metallurgical performance throughout the deposit. Understanding the spatial variability\nof Ni deportment in recoverable and non-recoverable phases through mineralogy is the key to understanding metallurgical performance, thus unlocking the value of the Dumont deposit and other large tonnage low-grade ultramafic nickel deposits.",
            "publicationTitle": "The Second AusIMM International Geometallurgy Conference, Brisbane, Queensland",
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            "title": "3D imaging of porosity modifying phases in Shuaiba Reservoir, Al Shaheen Field",
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                    "firstName": "T",
                    "lastName": "Solling"
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            "abstractNote": "Carbonate reservoir rocks often possess highly complex pore spaces, exhibiting extreme heterogeneity in the size, shape and connectivity of their pores at multiple scales. These variable features strongly impact oil recovery and pose severe challenges to reliable measurement and simulation of flow properties. As a complement to parallel studies of the plugs by conventional petrographic and core analysis techniques, a set of samples from four wells in the Shuaiba reservoir of the Al Shaheen field was analysed by 2D mineral mapping (from QEMSCAN) of polished plug sections, and by 3D tomographic mapping (from micro-CT) of subsampled mini-plugs, as a complement to parallel studies of the plugs by conventional petrographic and core analysis techniques. QEMSCAN showed a high variability in measured porosity and pyrite content over all sampled length scales, from millimetres (across the polished plug faces) to feet (with depth in a given well) to kilometres (across the four wells). The porosity from QEMSCAN was generally found to be in good agreement with that measured on the conventional plugs. Two mini-plugs of 5 mm diameter were scanned using helical micro-CT, one of which was subsequently analysed to segment the macropores, microporosity, calcite and pyrite. Comparison with the QEMSCAN results from the section of the \"parent?? plug showed consistency in estimated porosity and pyrite content between the two methods. Simulations of conductivity and absolute permeability were performed on subvolumes of the segmented tomogram, and displayed a strong variability with the location and size of the chosen subvolume, although the overall trends remained in good agreement with core analysis.",
            "proceedingsTitle": "IPTC-17673-MS",
            "conferenceName": "International Petroleum Technology Conference, 19-22 January, Doha, Qatar",
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            "title": "Paragenesis and composition of ore minerals in the Randalls BIF-hosted gold deposits, Yilgarn Craton, Western Australia: Implications for the timing of deposit formation and constraints on gold sources",
            "creators": [
                {
                    "creatorType": "author",
                    "firstName": "Jeffrey A.",
                    "lastName": "Steadman"
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                {
                    "creatorType": "author",
                    "firstName": "Ross R.",
                    "lastName": "Large"
                },
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                    "creatorType": "author",
                    "firstName": "Garry J.",
                    "lastName": "Davidson"
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                    "creatorType": "author",
                    "firstName": "Stuart W.",
                    "lastName": "Bull"
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                    "creatorType": "author",
                    "firstName": "Jay",
                    "lastName": "Thompson"
                },
                {
                    "creatorType": "author",
                    "firstName": "Trevor R.",
                    "lastName": "Ireland"
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                    "creatorType": "author",
                    "firstName": "Peter",
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            "abstractNote": "The Randalls district comprises three individual gold deposits – Cock-Eyed Bob, Maxwells, and Santa-Craze – hosted in the same unit of banded iron-formation (BIF) in the southern Eastern Goldfields Superterrane, Yilgarn Craton, Western Australia. The iron formation is a silicate/oxide-facies unit with overprinting sulfides, and has undergone metamorphism (upper-greenschist facies) and deformation (two generations of folds). The gold deposits are hosted in two structural locations: hinge zones of anticlinal folds (e.g., Santa-Craze and Maxwells) and overturned, steeply dipping limbs of anticlinal folds (e.g., Cock-Eyed Bob). Gold dominantly occurs as inclusions of native gold and/or electrum within or around pyrrhotite, magnetite, and arsenopyrite.\n\nThe earliest mineral assemblage preserved in the banded iron formation at Randalls is banded magnetite–quartz. Magnetite in all forms has elevated Mg, Al, Ti, V, Mn, Cr, Zn, and W, but very low Ni compared to other BIFs globally. Pyrrhotite, the most abundant sulfide, is restricted to ore zones and occurs as laminae, “blebs”, and veinlets, all of which have replaced magnetite. Some pyrrhotite in the hydrothermally altered BIFs (especially in near-surface samples) has been re-sulfidized to pyrite. Trace elements associated with pyrrhotite include Co, Ni, Ag, Sb, and Pb. Large, coarse-grained arsenopyrite overgrows the pyrrhotite-defined foliation; it is enriched in Co, Ni, Sb, and Te, but contains very little ‘invisible’ gold (<0.01 ppm Au), unlike arsenopyrite in many orogenic Au systems globally (commonly ≥0.1 ppm Au).\n\nPetrographic studies of several mineralized BIFs from Randalls reveal that pyrrhotite and arsenopyrite are associated with Fe(-Ca) amphibole, which grew during contact metamorphism caused by granite plutons. This spatial sulfide–amphibole relationship indicates that gold mineralization likely occurred during granite intrusion, consistent with prior studies on Randalls. The trace element characteristics of the sulfides show that they were not inherited from replaced magnetite. Further, these characteristics suggest that the fluid from which sulfides crystallized was not indigenous to the BIFs, and that this S-rich fluid either contained S in abundance originally, or interacted with a lithology/lithologies that were rich in S before reaching the BIFs. Black shale containing diagenetic nodular pyrite occurs in the upper Black Flag Group, which unconformably underlies the Belches Supersequence at depth (∼3 km). The trace element composition of nodular pyrite from this unit fits well with the trace element characteristics of the BIF pyrrhotite and arsenopyrite, and the nodular pyrite contains an average of 0.5 ppm Au. However, the nodular pyrites have an average δ34S value of 5.6‰ (n = 13), which contrasts markedly with the δ34S average of pyrrhotite, pyrite and arsenopyrite in mineralized BIFs (0.8‰, n = 17). Thus, a definitive source of gold, arsenic, silver, and tellurium in the Randalls system remains elusive, although we would contend that the upper Black Flag Group should be considered as a possible metal and S source in areas of the Yilgarn where it forms a thick substrate to ore camps.",
            "publicationTitle": "Precambrian Research",
            "publisher": "",
            "place": "",
            "date": "2014",
            "volume": "243",
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            "DOI": "10.1016/j.precamres.2014.01.002",
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            "ISSN": "03019268",
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            "shortTitle": "Paragenesis and composition of ore minerals in the Randalls BIF-hosted gold deposits, Yilgarn Craton, Western Australia",
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            "creatorSummary": "Ruiz et al.",
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            "title": "Galvanic Effect of Pyrite on Chalcopyrite Leaching in Sulfate-Chloride Media",
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                    "firstName": "M. C.",
                    "lastName": "Ruiz"
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            "abstractNote": "Chalcopyrite concentrate and mixtures of pyrite/chalcopyrite were leached in H2SO4- NaCl-O2 solutions to assess the effect of pyrite on the chalcopyrite dissolution rate in this media. The results showed that the addition of pyrite increases the dissolution rate of chalcopyrite at short leaching times but the catalytic effect of pyrite decreases as the reaction progresses. Based on the experimental evidence it was concluded that the presence of pyrite in the leaching of chalcopyrite in H2SO4- NaCl-O2 solutions enhances the dissolution of copper through a galvanic interaction between pyrite and chalcopyrite. Additions of ferrous sulfate also increase chalcopyrite leaching rate effectively.",
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                    "lastName": "Marquez"
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                    "lastName": "Solling"
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